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RS 危险和安全代码

(European Union Commission Directive 2001/59/EC defines hazard codes and phrases for classification, packaging and labeling of dangerous substances.For complete hazard and safety information always refer to the MSDS)

Risk Phrases

Indication of Particular Risks

R1:Explosive when dry
2:Risk of explosion by shock, friction, fire or other sources of ignition
3:Extreme risk of explosion by shock, friction, fire or other sources of ignition
4:Forms very sensitive explosive metallic compounds
5:Heating may cause an explosion
6:Explosive with or without contact with air
7:May cause fire
8:Contact with combustible material may cause fire
9:Explosive when mixed with combustible material
10:Flammable
11:Highly Flammable
12:Extremely Flammable
14:Reacts violently with water
15:Contact with water liberates extremely flammable gases
16:Explosive when mixed with oxidizing substances
17:Spontaneously flammable in air
18:In use may form flammable/explosive vapor-air mixture
19:May form explosive peroxides
20:Harmful by inhalation
21:Harmful in contact with skin
22:Harmful if swallowed
23:Toxic by inhalation
24:Toxic in contact with skin
25:Toxic if swallowed
26:Very Toxic by inhalation
27:Very Toxic in contact with skin
28:Very Toxic if swallowed
29:Contact with water liberates toxic gas
30:Can become highly flammable in use
31:Contact with acids liberates toxic gas
32:Contact with acids liberates very toxic gas
33:Danger of cumulative effects
34:Causes burns
35:Causes severe burns
36:Irritating to the eyes
37:Irritating to the respiratory system
38:Irritating to the skin
39:Danger of very serious irreversible effects
40:Limited evidence of a carcinogenic effect
41:Risk of serious damage to eyes
42:May cause sensitization by inhalation
43:May cause sensitization by skin contact
44:Risk of explosion if heated under confinement
45:May cause cancer
46:May cause heritable genetic damage
48:Danger of serious damage to health by prolonged exposure
49:May cause cancer by inhalation
50:Very Toxic to aquatic organisms
51:Toxic to aquatic organisms
52:Harmful to aquatic organisms
53:May cause long-term adverse effects in the aquatic environment
54:Toxic to flora
55:Toxic to fauna
56:Toxic to soil organisms
57:Toxic to bees
58:May cause long-term adverse effects in the environment
59:Dangerous for the ozone layer
60:May impair fertility
61:May cause harm to the unborn child
62:Possible risk of impaired fertility
63:Possible risk of harm to the unborn child
64:May cause harm to breast-fed babies
65:Harmful: May cause lung damage if swallowed
66:Repeated exposure may cause skin dryness or cracking
67:Vapors may cause drowsiness and dizziness
68:Possible risk of irreversible effects

Combination of Particular Risks

R14/15:Reacts violently with water, liberating extremely flammable gases
15/29:Contact with water liberates toxic, extremely flammable gas
20/21:Harmful by inhalation and in contact with skin
20/21/22:Harmful by inhalation, in contact with skin and if swallowed
20/22:Harmful by inhalation and if swallowed
21/22:Harmful in contact with skin and if swallowed
23/24:Toxic by inhalation and in contact with skin
23/24/25:Toxic by inhalation, in contact with skin and if swallowed
23/25:Toxic by inhalation and if swallowed
24/25:Toxic in contact with skin and if swallowed
26/27:Very Toxic by inhalation and in contact with skin
26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed
26/28:Very Toxic by inhalation and if swallowed
27/28:Very Toxic in contact with skin and if swallowed
36/37:Irritating to eyes and respiratory system
36/37/38:Irritating to eyes, respiratory system and skin
36/38:Irritating to eyes and skin
37/38:Irritating to respiratory system and skin
39/23:Toxic: danger of very serious irreversible effects through inhalation
39/23/24:Toxic: danger of very serious irreversible effects through inhalation in contact with skin
39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/23/25:Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/24:Toxic: danger of very serious irreversible effects in contact with skin
39/24/25:Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/25:Toxic: danger of very serious irreversible effects if swallowed
39/26:Very Toxic: danger of very serious irreversible effects through inhalation
39/26/27:Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
39/26/27/28:Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/26/28:Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/27:Very Toxic: danger of very serious irreversible effects in contact with skin
39/27/28:Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/28:Very Toxic: danger of very serious irreversible effects if swallowed
42/43:May cause sensitization by inhalation and skin contact
48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation
48/20/21:Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/20/21/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
48/20/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/21:Harmful: danger of serious damage to health by prolonged exposure in contact with skin
48/21/22:Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed
48/23:Toxic: danger of serious damage to health by prolonged exposure through inhalation
48/23/24:Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/23/24/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
48/23/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/24:Toxic: danger of serious damage to health by prolonged exposure in contact with skin
48/24/25:Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/25:Toxic: danger of serious damage to health by prolonged exposure if swallowed
50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
68/20:Harmful: possible risk of irreversible effects through inhalation
68/20/21:Harmful: possible risk of irreversible effects through inhalation and in contact with skin
68/20/21/22:Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
68/20/22:Harmful: possible risk of irreversible effects through inhalation and if swallowed
68/22:Harmful: possible risk of irreversible effects if swallowed
68/21:Harmful: possible risk of irreversible effects in contact with skin
68/21/22:Harmful: possible risk of irreversible effects in contact with skin and if swallowed
68/22:Harmful: possible risk of irreversible effects if swallowed

 


Safety Phrases

Indication of Safety Precautions

S1:Keep locked up
2:Keep out of the reach of children
3:Keep in a cool place
4:Keep away from living quarters
5:Keep contents under … (appropriate liquid to be specified by the manufacturer)
6:Keep under … (inert gas to be specified by the manufacturer)
7:Keep container tightly closed
8:Keep container dry
9:Keep container in a well-ventilated place
12:Do not keep the container sealed
13:Keep away from food, drink and animal feeding stuffs
14:Keep away from … (incompatible materials to be indicated by the manufacturer)
15:Keep away from heat
16:Keep away from sources of ignition – No smoking
17:Keep away from combustible material
18:Handle and open container with care
20:When using, do not eat or drink
21:When using, do not smoke
22:Do not breathe dust
23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24:Avoid contact with skin
25:Avoid contact with eyes
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27:Take off immediately all contaminated clothing
28:After contact with skin, wash immediately with plenty of … (to be specified by the manufacturer)
29:Do not empty into drains
30:Never add water to this product
33:Take precautionary measures against static discharges
35:This material and its container must be disposed of in a safe way
36:Wear suitable protective clothing
37:Wear suitable gloves
38:In case of insufficient ventilation, wear suitable respiratory equipment
39:Wear eye/face protection
40:To clean the floor and all objects contaminated by this material use … (to be specified by the manufacturer)
41:In case of fire and/or explosion do not breathe fumes
42:During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
43:In case of fire, use … (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add – Never use water)
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
46:If swallowed, seek medical advice immediately and show this container or label
47:Keep at temperature not exceeding … E C (to be specified by the manufacturer)
48:Keep wetted with … (appropriate material to be specified by the manufacturer)
49:Keep only in the original container
50:Do not mix with … (to be specified by the manufacturer)
51:Use only in well-ventilated areas
52:Not recommended for interior use on large surface areas
53:Avoid exposure – obtain special instruction before use
56:Dispose of this material and its container to hazardous or special waste collection point
57:Use appropriate container to avoid environmental contamination
59:Refer to manufacturer/supplier for information on recovery/recycling
60:This material and/or its container must be disposed of as hazardous waste
61:Avoid release to the environment. Refer to special instructions safety data sheet
62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
63:In case of accident by inhalation, remove casualty to fresh air and keep at rest
64:If swallowed, rinse mouth with water (only if the person is conscious)

Combination of Safety Precautions

1/2:Keep locked up and out of the reach of children
3/7:Keep container tightly closed in a cool place
3/9/14:Keep in a cool well-ventilated place away from … (incompatible materials to be indicated by manufacturer)
3/9/14/49:Keep only in the original container in a cool well-ventilated place away from … (incompatible materials to be indicated by manufacturer)
3/9/49:Keep only in the original container in a cool well-ventilated place
3/14:Keep in a cool place away from … (incompatible materials to be indicated by the manufacturer)
7/8:Keep container tightly closed and dry
7/9:Keep container tightly closed and in a well-ventilated place
7/47:Keep container tightly closed and at a temperature not exceeding … °C (to be specified by manufacturer)
20/21:When using, do not eat, drink or smoke
24/25:Avoid contact with skin and eyes
27/28:After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of…. (to be specified by the manufacturer)
29/35:Do not empty into drains, dispose of this container and it’s material in a safe way
29/56:Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
36/37:Wear suitable protective clothing and gloves
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
36/39:Wear suitable protective clothing and eye/face protection
37/39:Wear suitable gloves and eye/face protection
47/49:Keep only in the original container at temperature not exceeding … °C (to be specified by manufacturer)

PICTOGRAMS AND HAZARD CODES

ExplosiveOxidizingExtremely
Flammable  or
Highly Flammable
Very Toxic or
Toxic
Harmful or
Irritant
CorrosiveDangerous for
the environment
BBiohazard
FHighly Flammable
F+Extremely Flammable
OOxidizing
CCorrosive
XnHarmful
XiIrritant
RRadioactive
EExplosiveNDangerous for the
environment
TToxic
T+Very Toxic

 

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